Yes, that is the bishop’s wife, but where is the bishop, and who is that man? The Bishop’s Wife, the 1947 film produced by Samuel Goldwyn and directed by Henry Coster, stars Cary Grant, Loretta Young, David Niven and Monty Woolley.
Where is the bishop? Cary Grant is supposed to be assisting the bishop, but he seems to be mostly assisting the bishop’s wife, until finally:
But, I’m an angel!